Search results for "anion-pi interactions"

showing 2 items of 2 documents

Experimental investigation of anion-π interactions : Applications and biochemical relevance

2015

Chemical communications 52(9), 1778 - 1795(2016). doi:10.1039/C5CC09072E

Anionsanion-pi interactionsSolid-stateChemieNanotechnology010402 general chemistry01 natural sciencesCatalysisIonGas phasekemialliset sidoksetTime frameMaterials Chemistrysupramolekulaarinen kemiaanioni-π-vuorovaikutus010405 organic chemistryChemistryIntermolecular forceMetals and AlloysGeneral Chemistry5400104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic Materialsintermolecular forcesnon-covalent interactionsChemical physicsddc:540Ceramics and Composites
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Perfluoro-1,1′-biphenyl and perfluoronaphthalene and their derivatives as π-acceptors for anions

2015

Addition of anions to perfluorinated 1,1′-biphenyl 1 or naphthalene 2 results in a shift of the 19F NMR signals. However, any specific interaction cannot be assigned to this effect. In order to study the interaction in more detail, the salt derivatives 3 and 4 were prepared and studied by single crystal X-ray diffraction revealing weak anion–π interactions in the solid state.

Diffractionchemistry.chemical_classificationBiphenylanion-pi interactionsSolid-stateSalt (chemistry)General ChemistryFluorine-19 NMRCatalysisIonCrystallographychemistry.chemical_compoundchemistryMaterials ChemistryOrganic chemistryta116Single crystalNaphthaleneNew Journal of Chemistry
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